Reisenauer, Hans PeterHans PeterReisenauerRomanski, JaroslawJaroslawRomanskiMloston, GrzegorzGrzegorzMlostonSchreiner, Peter R.Peter R.Schreiner2023-06-022020-05-202023-06-022013http://nbn-resolving.de/urn:nbn:de:hebis:26-opus-151354https://jlupub.ub.uni-giessen.de/handle/jlupub/16367http://dx.doi.org/10.22029/jlupub-15747The atmospherically highly relevantmethylsulfinyl radical CH3(O)S-center dot was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S-center dot and its D3- and C-13- isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.enNamensnennung 3.0 Internationalddc:540