Deng, GuohaiGuohaiDengPorto, Caio M.Caio M.PortoMardyukov, ArturArturMardyukovSchreiner, Peter RichardPeter RichardSchreiner2025-05-232025-05-232025https://jlupub.ub.uni-giessen.de/handle/jlupub/20551https://doi.org/10.22029/jlupub-19899We describe the first spectroscopic identification of hitherto experimentally unreported hydroxy isocyanate HONCO, a potential candidate for the interstellar medium and prebiotic chemistry. This planar chain molecule was prepared in the gas phase through flash vacuum pyrolysis of phenyl N-hydroxycarbamate at 650 °C and was subsequently trapped in argon matrices at 3.5 K. Its characterization was accomplished by means of matrix isolation IR and UV/Vis spectroscopy together with quantum chemical calculations. Upon the UV light (λ = 313 nm) irradiation, HONCO decomposes into hydrogen-bonded complexes of HON and HNO with CO.enCC0 1.0 UniversalIsocyanateMatrix-isolationPhotochemistryPrebiotic moleculesPyrolysisddc:540