Janek, JürgenJürgenJanek2023-06-122005-09-132023-06-122000http://nbn-resolving.de/urn:nbn:de:hebis:26-opus-23784https://jlupub.ub.uni-giessen.de/handle/jlupub/16723http://dx.doi.org/10.22029/jlupub-16101The transfer of matter and charge across interfaces between two solids is related to defect relaxation in the regions near the interface. A transfer rate which exceeds the rate of defect relaxation may lead to degradation of the interface, causing a feedback effect for the transfer process itself. As a consequence, non-linear phenomena (dissipative structures) like periodic oscillations of the interfacial properties can occur under conditions far from equilibrium. Possible mechanisms and experimental examples are discussed.enIn CopyrightDissipative structuresElectrochemical oscillationsInterfacesIonic conductorsPoint defectsddc:540Oscillatory kinetics at solid/solid phase boundaries in ionic crystals