Janek, JürgenJürgenJanek2023-06-122005-09-122023-06-121997http://nbn-resolving.de/urn:nbn:de:hebis:26-opus-23743https://jlupub.ub.uni-giessen.de/handle/jlupub/16720http://dx.doi.org/10.22029/jlupub-16098The transfer of matter and charge across interfaces between two solids is generally related to processes of defect relaxation in the regions near the interface. A transfer rate which exceeds the rate of defect relaxation may lead to degradation of the interface, causing a feedback effect for the transfer itself. As a consequence, non-linear phenomena (dissipative structures) like periodic oscillations of the interfacial properties can occur under conditions far from equilibrium. Experimental examples are discussed.enIn CopyrightDissipative structuresElectrochemical oscillationsInterfacesIonic conductorsPoint defectsddc:540Oscillating reactions at metal electrodes in solid electrolytes