The functionalization of nanodiamonds (diamondoids) as a key parameter of their easily controlled self-assembly in micro- and nanocrystals from the vapor phase
dc.contributor.author | Gunawan, Maria A. | |
dc.contributor.author | Poinsot, Didier | |
dc.contributor.author | Domenichini, Bruno | |
dc.contributor.author | Dirand, Celine | |
dc.contributor.author | Chevalier, Sebastien | |
dc.contributor.author | Fokin, Andrey A. | |
dc.contributor.author | Schreiner, Peter R. | |
dc.contributor.author | Hierso, Jean-Cyrille | |
dc.date.accessioned | 2023-06-02T13:38:25Z | |
dc.date.available | 2015-03-25T13:38:28Z | |
dc.date.available | 2023-06-02T13:38:25Z | |
dc.date.issued | 2014 | |
dc.description.abstract | We detail herein readily accessible processes to control previously unobserved robust self-assemblies of nanodiamonds (diamondoids) in micro- and nanocrystals from their mild vapor deposition. The chemical functionalization of uniform and discernible nanodiamonds was found to be a key parameter, and depending on the type of functional group (hydroxy, fluorine, etc.) and its position on the diamondoid, the structure of the discrete deposits can vary dramatically. Thus, well-defined anisotropic structures such as rod, needle, triangle or truncated octahedron shapes can be obtained, and self-assembled edifices of sizes ranging from 20 nm to several hundred micrometers formed with conservation of a similar structure for a given diamondoid. Key thermodynamic data including sublimation enthalpy of diamondoid derivatives are reported, and the SEM of the self-assemblies coupled with EDX analyses and XRD attest the nature and purity of nanodiamond crystal deposits. This attractive method is simple and outperforms in terms of deposit quality dip-coating methods we used. This vapor phase deposition approach is expected to allow for an easy formation of diamondoid nanoobjects on different types of substrates. | en |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:hebis:26-opus-114076 | |
dc.identifier.uri | https://jlupub.ub.uni-giessen.de//handle/jlupub/16479 | |
dc.identifier.uri | http://dx.doi.org/10.22029/jlupub-15859 | |
dc.language.iso | en | de_DE |
dc.rights | Namensnennung 3.0 International | * |
dc.rights.uri | https://creativecommons.org/licenses/by/3.0/?la=de | * |
dc.subject.ddc | ddc:540 | de_DE |
dc.title | The functionalization of nanodiamonds (diamondoids) as a key parameter of their easily controlled self-assembly in micro- and nanocrystals from the vapor phase | en |
dc.type | article | de_DE |
local.affiliation | FB 08 - Biologie und Chemie | de_DE |
local.comment | RSC Open Access Artikel | |
local.opus.fachgebiet | Chemie | de_DE |
local.opus.id | 11407 | |
local.opus.institute | Institut für Organische Chemie | de_DE |
local.source.freetext | Nanoscale 7(5):1956-1962 doi:10.1039/C4NR04442H | de_DE |
local.source.uri | https://doi.org/10.1039/C4NR04442H |
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