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dc.contributor.authorMüller, Tizian
dc.contributor.authorHasenbeck, Max
dc.contributor.authorBecker, Jonathan
dc.contributor.authorGellrich, Urs
dc.date.accessioned2023-12-01T13:21:04Z
dc.date.available2023-12-01T13:21:04Z
dc.date.issued2023
dc.identifier.urihttps://jlupub.ub.uni-giessen.de//handle/jlupub/18725
dc.identifier.urihttp://dx.doi.org/10.22029/jlupub-18089
dc.description.abstractWe report here the formation of the bridged boracycle 1 upon reaction of cyclooctatetraene with bis(pentafluorophenyl)borane. Computations indicate that the reaction commences with a hydroboration and that the high Lewis acidity of the bis(pentafluorophenyl)borane then induces a rearrangement with cleavage of a carbon–carbon bond via a nonclassical zwitterion and a final 1,1-carboboration. An intermediate of the reaction was captured as tri-tert-butylphosphine adduct.
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG); ROR-ID:018mejw64
dc.language.isoen
dc.rightsNamensnennung - Nicht kommerziell 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subjectHydroboration
dc.subjectCarboboration
dc.subjectRearrangement
dc.subjectDensity functional calculations
dc.subjectLewis acid
dc.subject.ddcddc:540
dc.titleBis(pentafluorophenyl)borane Induced Tandem Hydroboration-Carboboration of Cyclooctatetraene
dc.typearticle
local.affiliationFB 08 - Biologie und Chemie
local.projectGE 3117/1-1
local.source.journaltitleZeitschrift für anorganische und allgemeine Chemie
local.source.volume649
local.source.number6-7
local.source.articlenumbere202200381
local.source.urihttps://doi.org/10.1002/zaac.202200381


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