Balancing Attraction and Repulsion: The Influence of London Dispersion in [10]Cycloparaphenylene-Fullerene Complexes

Kurzanzeige
dc.contributor.authorVolkmann, Jannis
dc.contributor.authorKohrs, Daniel
dc.contributor.authorWegner, Hermann A.
dc.date.accessioned2023-12-06T13:21:43Z
dc.date.available2023-12-06T13:21:43Z
dc.date.issued2023
dc.description.abstractHerein we present a systematic study of the influence of different alkyl chains in malonyl ester fullerene adducts with [10]cycloparaphenylene ([10]CPP]) and a tert-butyl (tBu) ester-substituted [10]CPP analogue. The association constants between the nanoring hosts and the fullerene guests were determined by fluorescence quenching experiments. The trends in association were rationalized by an interplay of repulsion arising from an extended volume and London dispersion as an attractive counterpart.
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG); ROR-ID:018mejw64
dc.identifier.urihttps://jlupub.ub.uni-giessen.de//handle/jlupub/18754
dc.identifier.urihttp://dx.doi.org/10.22029/jlupub-18118
dc.language.isoen
dc.rightsNamensnennung - Nicht kommerziell 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subjectcyclophanes
dc.subjectfullerenes
dc.subjecthost-guest systems
dc.subjectpi interactions
dc.subjectsupramolecular chemistry
dc.subject.ddcddc:540
dc.titleBalancing Attraction and Repulsion: The Influence of London Dispersion in [10]Cycloparaphenylene-Fullerene Complexes
dc.typearticle
local.affiliationFB 08 - Biologie und Chemie
local.projectSPP 1807
local.source.articlenumbere202300268
local.source.journaltitleChemistry - a European journal
local.source.urihttps://doi.org/10.1002/chem.202300268
local.source.volume29

Dateien

Originalbündel
Gerade angezeigt 1 - 1 von 1
Vorschaubild
Name:
10.1002_chem.202300268.pdf
Größe:
1.25 MB
Format:
Adobe Portable Document Format
Beschreibung:
Herunterladen

Sammlungen

Publikationen im Open Access gefördert durch die UB