Photochemically Mediated Toluene Oxidation through a Copper Complex

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dc.contributor.authorNoß, Christian
dc.contributor.authorGöttlich, Richard
dc.contributor.authorSchindler, Siegfried
dc.date.accessioned2023-12-06T13:12:12Z
dc.date.available2023-12-06T13:12:12Z
dc.date.issued2023
dc.description.abstractA method is described to photochemically oxidize toluene selectively to benzaldehyde, an essential compound in the chemical industry. Copper(I) complexes with different ligands were applied in combination with [Ru(bipy)3](PF6)2 and dioxygen as the oxidant. As a result, a “dioxygen adduct” copper complex, for example, a peroxido complex, is formed as the active species. The copper(II) complex obtained after oxidation can be photochemically reduced to the starting copper(I) species, and the process can be repeated continuously. The ligand tris(2-methylpyridyl)amine (tmpa) led to the highest conversion rates.
dc.identifier.urihttps://jlupub.ub.uni-giessen.de//handle/jlupub/18752
dc.identifier.urihttp://dx.doi.org/10.22029/jlupub-18116
dc.language.isoen
dc.rightsNamensnennung - Nicht kommerziell 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subjectcopper peroxido complexes
dc.subjectphotooxidation
dc.subjectbenzaldehyde
dc.subjecttoluene oxidation
dc.subjectruthenium bipyridine
dc.subject.ddcddc:540
dc.titlePhotochemically Mediated Toluene Oxidation through a Copper Complex
dc.typearticle
local.affiliationFB 08 - Biologie und Chemie
local.source.articlenumbere202301142
local.source.journaltitleChemistry - a European journal
local.source.urihttps://doi.org/10.1002/chem.202301142
local.source.volume29

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