Spatially resolved measurements of electrochemically induced spillover on porous and microstructured Pt/YSZ catalysts

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2000

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Herausgeber

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Pt/YSZ electrodes prepared from platinum (Pt) and yttria-stabilized zirconia (YSZ) can be applied in electrocatalytic experiments for the promotion of different heterogeneously catalyzed reactions. The strong increase in catalytic activity of Pt/YSZ assemblies on electrochemical polarisation has recently been attributed to the creation of catalytically active spill-over species under non-equilibrium conditions. Our experiments combine locally resolved surface sensitive techniques (SPEM, PEEM) with electrochemical methods in order to resolve the processes at the Pt/YSZ interface and to clarify the nature of the spillover species.

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undefined (2000)

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Zuerst erschienen in: Solid State Ionics 136 (2000) 699-705: http://dx.doi.org/10.1016/S0167-2738(00)00565-8

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