The enol of isobutyric acid

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dc.contributor.authorDanho, Akkad
dc.contributor.authorMardyukov, Artur
dc.contributor.authorSchreiner, Peter R.
dc.date.accessioned2025-11-18T11:04:19Z
dc.date.available2025-11-18T11:04:19Z
dc.date.issued2024
dc.description.abstractWe present the gas-phase synthesis of 2-methyl-prop-1-ene-1,1-diol, an unreported higher energy tautomer of isobutyric acid. The enol was captured in an argon matrix at 3.5 K, characterized spectroscopically and by DFT computations. The enol rearranges likely photochemically to isobutyric acid and dimethylketene. We also identified propene, likely photochemically formed from dimethylketene.en
dc.identifier.urihttps://jlupub.ub.uni-giessen.de/handle/jlupub/21059
dc.identifier.urihttps://doi.org/10.22029/jlupub-20408
dc.language.isoen
dc.rightsNamensnennung 3.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subject.ddcddc:540
dc.titleThe enol of isobutyric acid
dc.typearticle
local.affiliationFB 08 - Biologie und Chemie
local.source.epage5164
local.source.journaltitleChemical communications
local.source.spage5161
local.source.urihttps://doi.org/10.1039/d4cc01140f
local.source.volume60

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