Redox mediation enabled by immobilised centres in the pores of a metal organic framework grown by liquid phase epitaxy

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Dragässer, André
Shekhah, Osama
Zybaylo, Olexandra
Shen, Cai
Buck, Manfred
Wöll, Christof
Schlettwein, Derck

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http://dx.doi.org/10.22029/jlupub-15777

Abstract

A layer of a metal organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

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Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich. This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.

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Chemical Communications 48(5):663 doi:10.1039/c1cc16580a

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