Oscillatory kinetics at solid/solid phase boundaries in ionic crystals
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Abstract
The transfer of matter and charge across interfaces between two solids is related to defect relaxation in the regions near the interface. A transfer rate which exceeds the rate of defect relaxation may lead to degradation of the interface, causing a feedback effect for the transfer process itself. As a consequence, non-linear phenomena (dissipative structures) like periodic oscillations of the interfacial properties can occur under conditions far from equilibrium. Possible mechanisms and experimental examples are discussed.Link to publications or other datasets
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Zuerst erschienen in: Solid State Ionics 131 (2000) 129-142: href=http://dx.doi.org/10.1016/S0167-2738(00)00628-7