Oscillating reactions at metal electrodes in solid electrolytes
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Abstract
The transfer of matter and charge across interfaces between two solids is generally related to processes of defect relaxation in the regions near the interface. A transfer rate which exceeds the rate of defect relaxation may lead to degradation of the interface, causing a feedback effect for the transfer itself. As a consequence, non-linear phenomena (dissipative structures) like periodic oscillations of the interfacial properties can occur under conditions far from equilibrium. Experimental examples are discussed.Link to publications or other datasets
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Zuerst erschienen in: Solid State Ionics 101-103 (1997) 721-727: http://dx.doi.org/10.1016/S0167-2738(97)00180-X