Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S
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DOI:
http://dx.doi.org/10.22029/jlupub-15747Abstract
The atmospherically highly relevantmethylsulfinyl radical CH3(O)S-center dot was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S-center dot and its D3- and C-13- isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.Link to publications or other datasets
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Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich. This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Original publication in
Chemical Communications, 49, 9467-9469, doi: 10.1039/c3cc45379k