Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S

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dc.contributor.authorReisenauer, Hans Peter
dc.contributor.authorRomanski, Jaroslaw
dc.contributor.authorMloston, Grzegorz
dc.contributor.authorSchreiner, Peter R.
dc.date.accessioned2023-06-02T13:37:37Z
dc.date.available2020-05-20T08:46:01Z
dc.date.available2023-06-02T13:37:37Z
dc.date.issued2013
dc.description.abstractThe atmospherically highly relevantmethylsulfinyl radical CH3(O)S-center dot was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S-center dot and its D3- and C-13- isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.en
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:hebis:26-opus-151354
dc.identifier.urihttps://jlupub.ub.uni-giessen.de//handle/jlupub/16367
dc.identifier.urihttp://dx.doi.org/10.22029/jlupub-15747
dc.language.isoende_DE
dc.rightsNamensnennung 3.0 International*
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/?la=de*
dc.subject.ddcddc:540de_DE
dc.titleMatrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)Sen
dc.typearticlede_DE
local.affiliationFB 08 - Biologie und Chemiede_DE
local.commentDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich. This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
local.opus.fachgebietChemiede_DE
local.opus.id15135
local.opus.instituteInstitute of Organic Chemistryde_DE
local.source.freetextChemical Communications, 49, 9467-9469, doi: 10.1039/c3cc45379kde_DE
local.source.urihttps://doi.org/10.1039/c3cc45379k

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